Safety data sheet according to 29cfr19101200 and ghs rev. This product has been classified in accordance with the hazard criteria of the controlled products regulations and the msds contains all of the information required by those regulations. Specifically, the rule requires the employer to use labels and material safety data sheets msdss to let employees know about the health hazards of working with methylene chloride. Prolonged or repeated skin contact may cause dermatitis. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. This colorless, volatile liquid with a moderately sweet aroma is widely used as a solvent. Dichloromethane is reported to completely biodegrade under aerobic conditions with sewage seed or activated sludge between 6 hours to 7 days. Eye and skin contact, ingestion, inhalation signs and symptoms of exposure. Although it is not miscible with water, it is polar, and miscible with many organic solvents. Hydrogen chloride chlorine phosgene oxides of carbon sensitivity to mechanical impact.
This file may not be suitable for users of assistive technology. Safety data sheet methylene chloride page 5 issued. Always wear recommended personal protective equipment. Spill, leak, fire, exposure or accident call chemtrec day or night 800 4249300. Sigmaaldrich 270997 page 2 of 8 h319 causes serious eye irritation. Methylene chloride, which is also called dichloromethane, is a volatile chemical that is produced and imported into the united states, with use estimated at over 260 million pounds per year. While every effort has been made to accurately describe this product, some of the data are obtained from sources beyond our direct supervision. Our msds database is an easy to use, do it yourself tool, and best of all. Page 1 of 2 material safety data sheet e m e r g e n c y for chemical emergency. Show this safety data sheet to the doctor in attendance.
Material safety data sheet university of louisville. Dichloromethane, methylene chloride, methylene dichloride catalog number. Do not allow product to contact skin, eyes and clothing. The data sheet may be written, printed or otherwise expressed, and must meet the availability, design and content requirements of whmis legislation. H373 may cause damage to organs liver, blood through prolonged or repeated exposure if swallowed. In case of skin contact wash off with soap and plenty of water. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Remove clothing immediately if pesticide gets inside. Skin contact wash off immediately with plenty of water for at least 15 minutes. Methylene chloride is metabolically converted to carbon monoxide after systemic absorption, which yields increased concentrations of carboxyhemoglobin in the blood.
Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Material safety datasheet 9sections section 1 product information product identifier drytype transformer whmis classification optional product use electrical manufacturers name hammond power solutions inc. Silane msds material safety data sheet for silane sih4 reference. Sigmaaldrich 319996 page 1 of 6 sigmaaldrich material safety data sheet version 4. Methylene chloride is predominantly used as a solvent in paint strippers and removers. Phe publications gateway number 2014790 pdf, 271kb, 14 pages. Component immediately dangerous to life health idlh methylene chloride dichloromethane 75092 2300 ppm idlh propylene oxide 75569 400 ppm idlh hazardous combustion products. Methylene chloride, also known as dichloromethane or dcm, is used as an industrial solvent and a paint stripper, and is often used in bathtub refinishing. However, we make no warranty of merchantibility or any other warranty, express or implied, wi th respect to such information, and we assum e no liability resulting from its use. Identification of the substancemixture and of the companyundertaking 1.
Methylene chloride is a colorless liquid with a sweetish odor. Toxic if inhaled, contact causes severe eye damage and skin irritation. Mean background concentrations in rural areas are 0. Will degrade by reaction with hydroxyl radicals with a half life of several months. May cause carboxyhemoglobinemia impairment of the bloods ability to transport oxygen. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy.
Revised september 26, 2018 radnor solvent based antispatter bulk sds page 1 of 6 safety data sheet section 1. If inhaled if breathed in, move person into fresh air. If this product is used in combination with other products, refer to the. Product and company identification product identifier. Dichloromethane dcm or methylene chloride is an organochloride compound with the formula c h 2 cl 2. Precautionary numberprecautionary statement p201obtain special instructions before use. Dichloromethane 75092 reasonably anticipated to be a human carcinogen. To my surprise, i could not find anything about the injection of this solvent, just information related to eye contact, skin contact, ingestion, and inhalation. Methylene chloride, which is also called dichloromethane or dcm, is a volatile chemical that is produced and imported into the united states, with use estimated at over 260 million pounds per yea r.
Safety data sheet dichloromethane lrg according to regulation ec no 19072006, annex ii section 1. While waiting at the hospital during the surgery, i started looking for information about dichloromethane injuries and its material safety data sheet msds see table 1. Dichloromethane ch2cl2 also known as methylene chloride chemical abstracts service cas number. Please ensure that this msds is given to, and explained to people using this product. Material safety data sheet n,ndimethylpropylamine issue 3. Sds of dichloromethane, safety data sheets, cas 75092. P202do not handle until all safety precautions have been read and understood. Environmental the product is not classed as environmentally hazardous.
Take out injured to fresh air and provide comfortable space for proper breathing. Other companies are charging thousands of dollars to set up. India veritas house, 70 mint road, fort, mumbai 400 001. Safety data sheet northwest missouri state university. July 3, 2007 the dow chemical company page 5 of 7 methylene chloride is practically nontoxic to aquatic organisms on an acute basis. Use a noncombustible material like vermiculite, sand or earth to soak up the product.
Follow the osha respirator regulations found in 29 cfr 1910. Use a nioshmsha or european standard en 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. All equipment used when handling the product must be grounded. Page 3 of 5 7 handling and storage precautions for safe handling.
Dichloromethane is a member of the class of chloromethanes that is methane in which two of the hydrogens have been replaced by chlorine. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. May cause pain, redness or swelling of the eyes and excessive blinking and tear production. Empty containers pose a fire risk, evaporate the residue under a fume hood. A dense, nonflammible colourless liquid at room temperature b. P264wash arms, hands and face thoroughly after handling. Can react dangerously with nitrogen tetroxide, liquid oxygen, potassium, sodium, sodiumpotassium alloys, lithium, potassium hydroxide with nmethylnnitroso urea, potassium tbutoxide, and finely powdered aluminum and magnesium. Other information revision b, june 2015 the information contained herein is provided in good faith and is believed to be correct as of the date hereof.
Its chemical abstracts service registry number is 75092. Page 6 10 supplying respirator such as a selfcontained breathing apparatus scba or a supplied air respirator sar in the positive pressure or continuous flow mode, or 2. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Health hazard data to the best of our knowledge, the chemical, physical, and toxico logical properties of this mixture have not. Clear, colourless liquid with strong formaldehyde odour. Safety data sheet dichloromethane bdh11 page 3 16 version 1. Avoid heat, flames, sparks and other sources of ignition. Reasonably anticipated to be a human carcinogen methylene chloride reproductive toxicity no. This section applies to all occupational exposures to methylene chloride mc, chemical abstracts service registry number 75092, in general industry, construction and shipyard employment. However, we make no representation as to the comprehensiveness or accuracy of the info rmation. Nausea, vomiting, headache, dizziness, drowsiness, eye irritation with possible damage. Odor is a poor indicator of possibly dangerous air concentrations of methylene chloride. Methylene chloride is used in pharmaceutical products and paint removers.
Sigmaaldrich offers a number of dichloromethane products. Methylene chloride mc means an organic compound with chemical formula, ch2cl2. Methylene chloride is a clear, colorless, volatile liquid with a mild etherlike odor that is completely miscible with a variety of solvents. Methods for cleaning up use only nonsparking tools. Material safety data sheet ethylene dichloride msds name. Dichloromethane page 4 of 14 incident management physicochemical properties cas number 75092 molecular weight 84. In case of skin contact wash off with soap and plenty of. Msds document number si000 revision dated 19 dec 00 in an emergency, call chemtrec at 8004249300 us toll free or 7035273887. Msds material safety data sheet foreign inventory status. Dichloromethane lrg human health suspected of causing cancer. Empty containers retain product residue and can be hazardous precautions for safe handling methane, dichlorodifluoro acgih tlv united states, 32017.
Product identifier product name dichloromethane lrg product number 1203 synonyms. Anesthetic effects can be observed at levels in the range of 500 ppm. Firstaid measures general advice if symptoms persist, call a physician. Methylene chloride revision date 28nov2019 eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Toxic by inhalation, in contact w ith skin and if swallowed.
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